Improvements from the TOC-V Series(TOC-VCSH/CPH/CSN/CPN

The TOC-L series provides even better functionality and operability than the popular TOC-V series. In addition, applications can be further enhanced by adopting new options such as a kit for small sample volumes and a high-salt sample combustion tube kit.

    TOC-VCSH/CPH/CSN/CPN TOC-LCSH/CPH/CSN/CPN
Measurement range CSH/CPH TC:4 μg/L - 25,000 mg/L TC:4 μg/L - 30,000 mg/L
IC:4 μg/L - 30,000 mg/L IC:4 μg/L - 35,000 mg/L
TN:5 μg/L - 4,000 mg/L TN:5 μg/L - 10,000 mg/L
CSN/CPN TC:50 μg/L - 25,000 mg/L TC:50 μg/L - 30,000 mg/L
IC:4 μg/L - 3,000 mg/L IC:4 μg/L - 3,000mg/L
TN:20 μg/L - 4,000 mg/L TN:20 μg/L - 10,000 mg/L
Priority water sampling when using an autosampler Common None Yes (maximum of 30 second reduction per sample with 3 measurements, Note 1)
COD/BOD conversion Common Function available (TOC-VCSH/CSNonly) Function available (all models)
Built-in LCD CSH/CSN Black and white TFT color
Number and type of data saved (standalone model) CSH/CSN

Measurement results: For 200 samples, average values only
Calibration curve: 25 max.

Measurement results: For 2,000 samples or more, all measurement results and peak data
Calibration curve: 60 max.
Output of data saved (standalone model) CSH/CSN Not available Capable of output to a USB memory stick
Printer CSH/CSN Built-in printer (thermal) Capable of using a PC USB printer (sold separately)
Validation support CPH/CPN
(PC software)
None Yes
PC connection Common RS232C USB
Carrier gas problem detection Common None Function available
Power consumption
(Weekly integrated value) Note 2
Common Approx. 20,000 Wh Approx. 12,700 Wh (36 % reduction)
External dimensions, weight Common TOC main unit:
W440 x D525 x H460 mm,Approx. 40 kg
TN unit added:
W600 x D525 x H460 mm, Approx. 48 kg
TOC main unit:
W340 x D660 x H480 mm,Approx. 35 kg
TOC main unit:
W340 x D660 x H480 mm, Approx. 35 kg
Autosampler cover Common Fitted cover With a two-part cover, adding vials is simplified
Kit for small sample volumes CSH/CPH None (sample consumption: 8 mL for 3 measurements) Yes (sample consumption: 5 mL for 3 measurements)
High-salt sample combustion tube kit Common None Yes
Halogen scrubber for high-salt samples (B-type halogen scrubber) Common No option available Option available

Note 1) Measurement conditions: 3 NPOC measurements per sample. Comparison of average measurement time per sample when measuring 20 samples.

Note 2) Comparison of integrated power consumption under 8 hours/day, 5 days/week usage conditions.

Improvements from the TOC-5000 Series

The TOC-L series adopts the 680°C Catalytic Combustion Oxidation Method, which was developed by Shimadzu and is now used worldwide. While providing an ultra wide range of 4 μg/L to 30,000 mg/L, these analyzers boast a detection limit of 4 μg/L through coordination with NDIR. This is the highest level of detection sensitivity available with the catalytic combustion oxidation method. In addition, the catalytic combustion oxidation method makes it possible to efficiently oxidize not only easily-decomposed, low-molecular-weight organic compounds, but also hard-to-decompose insoluble and macromolecular organic compounds.

  TOC-5000(A) TOC-LCSH/CPH
Measurement range 4μg/L to 4,000mg/L 4 μg/L to 30,000 mg/L
(significantly extended thanks to the automatic dilution function)
Automatic dilution None Yes, the dilution function can reduce the sample acidity, alkalinity, and salinity, extending the period of use of catalysts and combustion tube.
NPOC measurement time
(No sampler)
10.5 minutes, sample fractionated into vials -> acid added -> sample set -> conditions set -> measurement 6.4 minutes (approx. 40 % reduction), sample set -> conditions set -> measurement
IC pretreatment Sparging only, automated treatment outside the analyzer Both the addition of acid and sparging performed automatically inside the analyzer
Rinsing water None, replacement rinsing by sample (rinsing with sample ) only Yes, capable of replacement rinsing by sample
(rinsing with sample), and cleaning by rinsing water (also used as dilution water)
COD/BOD conversion Function not available Function not available
Total nitrogen measurement Not available Available with TNM-L (option);
capable of simultaneous TOC and TN measurement
Built-in LCD Black and white TFT color (TOC-LCSH, TOC-LCSN)
Accuracy control function None Available with PC-controlled model
ER/ES None Available with PC-controlled model
(ER/ES: Electronic record / electronic signature)
Number and type of data saved Measurement results: 200 sample average values can be saved All measurement results including peak data for 2,000 or more samples, as well as up to 60 calibration curves (TOC-LCSH)
Output of saved data Not available Capable of output to a USB memory stick (TOC-LCSH)
NDIR light intensity adjustment Required Not required (automatic adjustment)
Carrier gas problem detection Function not available Function available
Main unit dimensions, weight W480×D500×H480mm,Approx.46kg W340×D660×H480mm,Approx.35kg
Autosampler sample vials ASI-5000A:5mL×78,42mL×16 (as well as STD 8), special vials used ASI-L:9mL×93,24mL×93,40mL×68,
Commercially-available vials used
Simple autosampler None set 8 samples can be set as standard, and up to 16 samples can be set with the unit added. Special vials are not needed, and water samples can be measured as is in their collection bottles.
Halogen scrubber for high-salt samples (B-type halogen scrubber) No option available Option available

TOC-LCSH

Model

High-sensitivity model

Operation method

Standalone

Measurement method

680°C catalytic combustion oxidation – non-dispersive infrared detection (NDIR) method

Measurement items

TO, IC, TOC, NPOC (Optional: POC, TN)

Measurement range TC

TC 0 to 30,000 mg/L

Measurement range IC

0 to 35,000 mg/L

Detection limit

4 µg/L

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TOC-LCPN

Model

Standard model

Operation method

PC-controlled

Measurement method

680°C catalytic combustion oxidation – non-dispersive infrared detection (NDIR) method

Measurement items

TO, IC, TOC, NPOC (Optional: POC, TN)

Measurement range TC

TC 0 to 30,000 mg/L

Measurement range IC

0 to 3,000 mg/L

Detection limit

50 µg/L

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TOC-LCSN

Model

Standard model

Operation method

Standalone

Measurement method

680°C catalytic combustion oxidation – non-dispersive infrared detection (NDIR) method

Measurement items

TO, IC, TOC, NPOC (Optional: POC, TN)

Measurement range TC

TC 0 to 30,000 mg/L

Measurement range IC

0 to 3,000 mg/L

Detection limit

50 µg/L

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TOC-LCPH

Model

High-sensitivity model

Operation method

PC-controlled

Measurement method

680°C catalytic combustion oxidation – non-dispersive infrared detection
(NDIR) method

Measurement items

TO, IC, TOC, NPOC (Optional: POC, TN)

Measurement range TC

TC 0 to 30,000 mg/L

Measurement range IC

0 to 35,000 mg/L

Detection limit

4 µg/L

Read more
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